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The lithium supply issue mainly lies in the inability of current mining methods to access lithium sources of dilute concentrations and complex chemistry. Electrochemical intercalation has emerged as a highly selective method for lithium extraction; however, limited source compositions have been studied, which is insufficient to predict its applicability to the wide range of unconventional water sources (UWS). This work addresses the feasibility and identifies the challenges of Li extraction by electrochemical intercalation from UWS, by answering three questions: 1) Is there enough Li in UWS? 2) How would the solution compositions affect the competition of Li + to major ions (Na + /Mg 2+ /K + /Ca 2+ )? 3) Does the complex solution composition affect the electrode stability? Using one-dimensional olivine FePO 4 as the model electrode, we show the complicated roles of major ions. Na + acts as the competitor ion for host storage sites. The competition from Na + grants Mg 2+ and Ca 2+ being only the spectator ions. However, Mg 2+ and Ca 2+ can significantly affect the charge transfer of Li + and Na + , therefore affecting the Li selectivity. We point to improving the selectivity of Li + to Na + as the key challenge for broadening the minable UWS using the olivine host. 

Since the start of science operations in 1993, the twin 10-meter W. M. Keck Observatory (WMKO) telescopes have continued to maximize their scientific impact and to produce transformative discoveries that keep the observing community on the frontiers of astronomical research. Upgraded capabilities and new instrumentation are provided though collaborative partnerships with Caltech, the University of California, and the University of Hawaii instrument development teams, as well as industry and other organizations. This paper summarizes the performance of recently commissioned infrastructure projects, technology upgrades, and new additions to the suite of observatory instrumentation. We also provide a status of projects currently in design or development phases and, since we keep our eye on the future, summarize projects in exploratory phases that originate from our 2022 strategic plan developed in collaboration with our science community to adapt and respond to evolving science needs. 

Since the start of science operations in 1993, the twin 10‐m W. M. Keck Observatory (WMKO) telescopes have continued to maximize their scientific impact and to produce transformative discoveries that keep the observing community on the frontiers of astronomical research. Upgraded capabilities and new instrumentation are provided through collaborative partnerships with Caltech, the University of California, and the University of Hawaii instrument development teams along with industry and other organizations. The observatory adapts and responds to the observers' evolving needs as defined in the observatory's strategic plan periodically refreshed in collaboration with the science community. This paper is an overview of the instrumentation projects that range from commissioning to early conceptual stages. An emphasis is placed on the detector, detector controllers, and capability needs that are driven by the desired future technology defined in the 2022 strategic plan.